So why does the OP dare to try it??
On the 2022 and 2023 Bolts, there is no shifter, it is just a button right next to the "pull button" that puts the car in drive. So there is little risk in pressing this button that you will mistakenly select reverse or park.
Also I would not recommend doing this at 45mph or greater, because if the hill is steep and long enough to maintain 45mph you might as well take advantage of the regen to charge your battery.
I think it is only useful only if you have a long gentle slope, a place where gravity can help you maintain speed or accelerate to your desired speed without having the regen interfere. Also if you are coming off of one small hill and you want to carry the speed from the hill a tenth of a mile or so to get up the next hill, neutral gear seems to be useful.