Yes, emergency stop shouldn't normally be used.Gotta finally comment here, in an attempt to reduce the chance that a rookie EV-and-DCFC user will resort to using the emergency stop button on the DCFC. With a DCFC session in progress (not already ended due to being at 100%), a strong and long push on the big plug's button should, as I understand, cause the EV to command the DCFC to bring the charger's DC current down to zero. Once that is done the Bolt will open the little shiny tab that is locking the big plug onto the Bolt's receptacle. The other ways of stopping the DCFC session and bringing the DC current to zero as already described above are also fine, of course.
In my experience this strong and long push on the plug's button might take 3 seconds, and if there is not too much ambient noise it might be possible to then hear the DCFC winding down (cooling fan?). That would confirm the DC current is down at zero and so now a pull would work to safely remove the plug. Could also bend down and look for that shiny tab to be in the up position to confirm that the lock is not in effect any more. The Bolt's design with this shiny locking tab is meant to hold the big plug in place and so prevent the user from interrupting a high DC current (an arc) by somehow forcing the plug off when the current is still above zero.
As for strong and long push, FWIW on the BTC Fatboy charger in the movie in post #3, I was surprised by the very fast, almost immediate release upon a quick and not strong press at all. It was almost identical in feel to just use J1772 AC handles (except those don't cause Bolt's silver locking tab to engage or disengage).