It doesn't matter who the person is, YouTube videos are a fundamentally inefficient form of communicating technical data.
Since I couldn't sleep and woke up early, I figured I'd indulge you by watching that video, which would normally take 1/4-1/3 of my entire morning time budget for "personal spare time" (emails, forums, etc.). I sometimes get more time during the day to check a forum while waiting for a compile job, but YouTube is a no-go there, same for during lunch breaks because mobile data pricing sucks.
The content first 4 minutes of the video could be read in less than a minute with a properly written spec sheet or technical article. In fact, there was an Electrek article in the past that covered the Bolt's battery. 288 prismatic cells in a 96S3P configuration, yadda yadda, nothing new in the video that isn't already known.
The only information given regarding the 12v system is a lead-acid battery (already known) and a 125 amp DCDC (already known).
For the purposes of this discussion, there are two key specifications:
1) 125A - this is the maximum capacity of the DCDC. This was covered in the video (given as wattage, but 125A at that output voltage is about 1600W) - and as we already established, this was a known specification without needing to spend 11 minutes watching a video with 1-2 minutes of content.
2) 50 Amp-hours - this is the capacity of the AGM battery, which isn't even covered in the video! (but already known from other sources)
Let's say you want to draw 50A from the system.
If the car is off, you'll flatten that battery in an hour. Do it more than a few times and it'll be sulfated
A LiFePO4 won't sulfate, but it's gonna cost you $575 just to match the capacity
In short, you NEED the car to be turned on and the DCDC active for your application. The built in battery type or capacity just doesn't matter at that point.
As far as how much inverter you can put on the system, people have been putting 1500W continuous-rated inverters on, but keep in mind those were for emergency power systems used rarely, not daily like you seem to be intending.
The DCDC's power budget is 125A (1600W) and you need to take into account that the same requirements for turning on the DCDC also mean that the vehicle is going to be using 12v power to run various things (like the infotainment system, etc.) - I'm not sure if this wattage can be seen by OBD, but it's likely to push the total power budget beyond the capabilities of the DCDC.
The DCDC isn't going to fail hard in this scenario, but it'll go into soft current limiting and the excess power will be drawn from the battery (as I've said multiple times before, its primary purpose is to absorb transients to make the DCDC's job easier, and to make power sequencing a bit easier for the engineers before the DCDC is active. Running a DCDC at very low loads is inefficient, so it likely winds up actually more efficient to periodically light it up to recharge the 12v battery than to leave it active at very low load.)
For a daily usage application like yours, I'd be careful about exceeding 750-1000W continuous load.
If you want more than this off of the 12v system you'll need to figure out how to make the Bolt's control electronics happy with the DCDC from a Volt, which is rated 165A.
One important question would be: Is the DCDC active in accessory mode? In a normal car, this is served by the alternator, which won't work if the engine isn't spinning. In an EV, it could be active in accessory mode, but is it? Oh yeah... That fairly important/useful piece of info isn't covered in the video either.